2-Methyl-3-nitrobenzonitrile
نویسندگان
چکیده
The asymmetric unit of the title compound, C(8)H(6)N(2)O(2), contains two independent mol-ecules, the aromatic rings of which are oriented at a dihedral angle of 1.68 (3)°. Intra-molecular C-H⋯O hydrogen bonds result in the formation of two non-planar six-membered rings, which adopt envelope and twisted conformations. In the crystal structure, inter-molecular C-H⋯O hydrogen bonds link the mol-ecules. There are π-π contacts between the benzene rings [centroid-centroid distances = 3.752 (3) and 3.874 (3) Å].
منابع مشابه
4-Methyl-3-nitrobenzonitrile
In the title compound, C(8)H(6)N(2)O(2), the nitro group is rotated by 23.2 (3)° out of the plane of the benzene ring. The crystal structure is stabilized by van der Waals inter-actions.
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In the title compound, C(8)H(6)N(2)O(2), the nitro group is rotated by 10.2 (2)° out of the plane of the benzene ring. The crystal structure is stabilized by van der Waals inter-actions.
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