P,N-Containing cyclophanes with large helical hydrophobic cavities: prospective precursors for the design of a molecular reactor.
نویسندگان
چکیده
The highly effective self-assembly process between 2,4,6-tris(isopropyl)phenylphosphine or mesitylphosphine, formaldehyde and 1,4-bis(alpha-(4'-aminophenyl)isopropyl)benzene results in the formation of a novel type of heterocyclophane which is able to encapsulate organic molecules as well as being a potential ligand for transition metals inside the intramolecular cavity. Compounds of this type can be regarded as potential precursors for a new kind of molecular reactors.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 3 شماره
صفحات -
تاریخ انتشار 2009