Gauge fields and extrapotentials in constrained quantum systems

We derive an effective Hamiltonian for a quantum system constrained to a submanifold ~the constraint manifold! of configuration space ~the ambient space! by an infinite restoring force. We pay special attention to how this Hamiltonian depends on quantities which are external to the constraint manifold, such as the extrinsic curvature of the constraint manifold, the curvature of the ambient space, and the constraining potential. In particular, we find the remarkable fact that the twisting of the constraining potential appears as a gauge potential in the constrained Hamiltonian. This gauge potential is closely related to the geometric phase originally discussed by Berry. The constrained Hamiltonian also contains an effective potential depending on the extrinsic curvature of the constraint manifold, the curvature of the ambient space, and the twisting of the constraining potential. The general nature of our analysis allows applications to a wide variety of problems, such as rigid molecules, the evolution of molecular systems along reaction paths, and quantum strip waveguides.