Chiral porous organic frameworks for asymmetric heterogeneous catalysis and gas chromatographic separation.
نویسندگان
چکیده
Three chiral robust diene-based porous organic frameworks (POFs) are prepared. POF- is shown to be an efficient heterogeneous catalyst after metallation for asymmetric conjugation addition with up to 93% ee, and it can also function as a new chiral stationary phase for gas chromatographic separation of racemates.
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 95 شماره
صفحات -
تاریخ انتشار 2014