Strategies for supercritical fluid extraction of polar and ionic compounds

نویسندگان

  • M. D. Luque de Castro
  • M. T. Tena
چکیده

The methods used to facilitate the supercritical fluid extraction (SFE) of polar and ionic compounds are based on two general principles, either increasing the polarity of the supercritical fluid (SF) (usually CO,) used as extractant or reducing the polarity of the analytes to be leached from the solid matrices. Changes in the pressure and temperature of the SF, the use of SFs more polar than CO, or of modified CO?, ion pair formation, esterification, the use of and organometallics, or complex formation are the most common ways of increasing the extraction efficiency for polar and ionic analytes.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Response surface methodology for optimization of supercritical fluid extraction of orange peel essential oil

Background: Orange peel essential oils were obtained using supercritical fluid extraction. This method is an important high scaling extraction methods that used for extraction of plant and animal extracts. Methodology: The experimental parameters of SFE such as temperature, pressure, and extraction time and modifier volume were optimized using a central composite design after a 24-1fractional ...

متن کامل

Extraction and Recovery of Polycyclic Aromatic Hydrocarbons in Petroleum Contaminated Soils Using Supercritical Water by Response Surface Methodology

Finding an environment-friendly and affordable method to remove contaminated soils from Polycyclic Aromatic Hydrocarbons (PAHs) has now become an attractive field for researchers, with super-critical fluid extraction being an innovative process in the field of contaminated soil treatment. Extraction with super-critical fluid is a simple and rapid extraction process that uses super-critical flui...

متن کامل

Separation of Pharmaceutical Enantiomers using Supercritical Fluid Technology

The use of supercritical fluids as chromatographic mobile phases provides rapid separations with high efficiency, favoring their use in enantioselective separations. Supercritical fluid technology (SFC) is a versatile tool in the purification, enantioseparation and large-scale production of enantiomers of pharmaceuticals over comparable liquid chromatographic methods and is gaining popularity i...

متن کامل

An Environmental Friendly Process for Extraction of Active Constituents from Herbal Plants

Conventional methods for extraction of the active constituents from herbal plants, in addition to their high processing costs, are harmful to the environment owing to their time and energy consumption, uncontrollable parameters, use of toxic and dangerous solvents, loss of the extract, thermal instability, the contamination of the product with organic solvents and the loss of water-soluble comp...

متن کامل

Supercritical Carbon Dioxide Extraction of Bioactive Compounds from Feijoa (Feijoa sellowiana) Leaves

Background and Objectives: Supercritical fluid extraction (SFE) technique has been studied for extraction of bioactive compounds from Feijoa sellowiana leaves. Results were compared with those obtained from conventional ethanolic extraction (CE). Materials and Methods: Results: The best supercritical carbon dioxide (SC-CO2) extraction conditions was determined as 250 bar of pressure, 50 &deg...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2003