Neptunium(III) copper(I) diselenide

نویسندگان

  • Daniel M. Wells
  • S. Skanthakumar
  • L. Soderholm
  • James A. Ibers
چکیده

The title compound, NpCuSe(2), is the first ternary neptunium transition-metal chalcogenide. It was synthesized from the elements at 873 K in an evacuated fused-silica tube. Single crystals were grown by vapor transport with I(2). NpCuSe(2) crystallizes in the LaCuS(2) structure type and can be viewed as a stacking of layers of CuSe(4) tetra-hedra and of double layers of NpSe(7) monocapped trigonal prisms along [100]. Because there are no Se-Se bonds in the structure, the formal oxidation states of Np/Cu/Se may be assigned as +III/+I/-II, respectively.

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عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009