Poly[[di-μ3-nicotinato-hemi-μ4-oxalato-hemi-μ2-oxalato-neodymium(III)silver(I)] dihydrate]

نویسندگان

  • Xiao-Yan Nie
  • Qian-Zhu Li
چکیده

The asymmetric unit of the title compound, {[AgNd(C(6)H(4)NO(2))(2)(C(2)O(4))]·2H(2)O}(n), contains one Nd(III) atom, one Ag(I) atom, one oxalate ligand, two nicotinate ligands and two uncoordinated water mol-ecules. The Nd(III) atom is eight-coordinated in a distorted square-anti-prismatic coordination geometry by four O atoms from two oxalate ligands and four O atoms from four nicotinate ligands. The Ag(I) atom has a T-shaped configuration, defined by two N atoms from two nicotinate ligands and one O atom from one oxalate ligand. The nicotinate and oxalate ligands link the Nd and Ag atoms into a three-dimensional coordination framework. O-H⋯O and O-H⋯N hydrogen bonds donated by water mol-ecules are observed in the crystal.

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The title of the paper by Zhu, Zhao & Yu [Acta Cryst. (2009), E65, m1105] is corrected.[This corrects the article DOI: 10.1107/S1600536809032115.].

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عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009