A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO2 adsorption.
نویسندگان
چکیده
The scandium analogue of the flexible terephthalate MIL-53 yields a novel closed pore structure upon removal of guest molecules which has unusual thermal behaviour and stepwise opening during CO(2) adsorption. By contrast, the nitro-functionalised MIL-53(Sc) cannot fully close and the structure possesses permanent porosity for CO(2).
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ورودعنوان ژورنال:
- Dalton transactions
دوره 41 14 شماره
صفحات -
تاریخ انتشار 2012