Blue rhenium tricarbonyl DPPZ complexes - low energy charge-transfer absorption at tissue-penetrating wavelengths.
نویسندگان
چکیده
fac-[Re(CO)3(dppz)] complexes of amido ligands generated in situ under basic conditions display an intense (ε = 16460 L mol-1 cm-1) absorption band between 500-700 nm which are assigned to an n(amido,RNH-) → π* (dppz) inter-ligand charge transfer band offering an extraordinarily low energy charge separating absorption with potential for imaging and energy application.
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ورودعنوان ژورنال:
- Chemical communications
دوره 52 84 شماره
صفحات -
تاریخ انتشار 2016