{2-[2-(Ethylamino)ethyliminomethyl]-5-methoxyphenolato}(thiocyanato-κN)copper(II)
نویسنده
چکیده
In the title mononuclear copper(II) complex, [Cu(C(12)H(17)N(2)O(2))(NCS)], the Cu(II) atom is four-coordinated by an NNO-donor set of the tridentate Schiff base ligand and the N atom of a terminal thio-cyanate ligand in a slightly distorted square-planar geometry.
منابع مشابه
{2-[2-(Ethylamino)ethyliminomethyl]-5-methoxyphenolato}thiocyanatonickel(II)
In the title mononuclear nickel(II) complex, [Ni(C(12)H(17)N(2)O(2))(NCS)], the metal atom is four-coordinated in a tetra-hedrally distorted square-planar geometry by the phenolate O atom, the imine N atom and the amine N atom of the Schiff base ligand and by the N atom of a thio-cyanate ligand. In the crystal structure, centrosymmetrically related mol-ecules are linked into dimers through inte...
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In the title compound, [Cu(C(13)H(17)BrClN(2)O)(NCS)], the Cu atom is in a slightly distorted square-planar geometry, coordinated by the three donor atoms of the ligand and the N atom of the isothio-cyanate group.
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In the title compound, [Cu(C(13)H(20)N(2)O(2))(2)](ClO(4))(2), the Cu(II) atom in the complex dication is chelated by two phenolate O atoms and two imine N atoms from two zwitterionic 2-[2-(isopropyl-ammonio)ethyl-imino-meth-yl]-5-methoxy-phenolate ligands, forming a distorted square-planar geometry. One of the perchlorate anions is disordered over two sites with occupancies of 0.611 (15) and 0...
متن کامل(1-{(E)-[Phenyl(pyridin-2-yl-κN)methylidene]amino-κN}pyrrolidin-2-one-κO)bis(thiocyanato-κN)copper(II)
The Cu(II) atom in the title compound, [Cu(NCS)(2)(C(16)H(15)N(3)O)], is bonded to the N atoms of two thio-cyanate ions, and is N,N'-chelated by the Schiff base ligand. The four N atoms surround the metal atom to form a distorted square; the square environment is distorted towards a square pyramid by a long Cu⋯O inter-action. In the crystal, two C atoms of the pyrrolidin-2-one ring are disorder...
متن کاملBis(2,2′-bipyridine-κ2 N,N′)(thiocyanato-κN)copper(II) perchlorate
The asymmetric unit of title compound, [Cu(NCS)(C(10)H(8)N(2))(2)]ClO(4), contains a bis-(2,2'-bipyridine)(isothio-cyanato)copper(II) cation and a perchlorate anion. In the cation, the Cu(2+) ion is coordinated by four N atoms from two bidentate 2,2'-bipyridine mol-ecules and an N atom from an isothio-cyanate anion, resulting in a distorted CuN(5) pyramidal configuration. The crystal structure ...
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