Nanopod formation through gold nanoparticle templated and catalyzed cross-linking of polymers bearing pendant propargyl ethers.
نویسندگان
چکیده
A novel method for synthesizing polymer nanopods from a linear polymer bearing pendant propargyl ether groups, using gold nanoparticles as both the template and the catalyst for the cross-linking reaction, is reported. The transformations involved in the cross-linking process are unprecedented on the surface of a gold particle. A tentative cross-linking mechanism is proposed.
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عنوان ژورنال:
- Journal of the American Chemical Society
دوره 132 43 شماره
صفحات -
تاریخ انتشار 2010