N′-[(2Z)-4-Oxo-4-phenyl­but-2-en-2-yl]pyridine-4-carbohydrazide

نویسندگان

  • Rahman Bikas
  • Parisa Mahboubi Anarjan
  • Sanam Aslekhademi
  • Seik Weng Ng
  • Edward R. T. Tiekink
چکیده

There are significant twists in the title compound, C(16)H(15)N(3)O(2), as seen in the dihedral angle between the benzene and adjacent but-2-enal group [29.26 (4)°] and between the pyridine ring and amide group [24.79 (6)°]. A twist is also evident around the hydrazine bond [the C-N-N-C torsion angle is -138.25 (13)°]. The conformation about the ethene bond is Z. An intra-molecular N-H⋯O hydrogen bond involving the benzoyl O atom and leading to an S(6) motif is formed. Significant delocalization of π-electron density is found in this part of the mol-ecule. In the crystal, helical supra-molecular chains aligned along the b axis and mediated by N-H⋯O hydrogen bonds are formed.

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عنوان ژورنال:

دوره 68  شماره 

صفحات  -

تاریخ انتشار 2012