Poly[[aqua­bis­[μ2-6-(pyridine-3-car­box­amido)­naphthalene-2-carboxyl­ato]copper(II)] dihydrate]

نویسندگان

  • Yun-Sung Song
  • Soon W. Lee
چکیده

The title compound, {[Cu(C(17)H(11)N(2)O(3))(2)(H(2)O)]·2H(2)O}(n), is a two-dimensional polymer. The Cu(2+) ion lies on the crystallographic twofold axis. The coordination sphere of the Cu(2+) ion can be described as a distorted square pyramid. All of the H atoms in the amide group and lattice water mol-ecules participate in O-H⋯O or N-H⋯O hydrogen bonding to strengthen the two-dimensioal framework of the polymer.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Poly[[(μ2-di-3-pyridyl­methanone-κ2 N:N′)(μ2-hexa­fluoro­silicato-κ2 F:F′)copper(II)] dihydrate]

In the title complex, {[Cu(SiF(6))(C(11)H(8)N(2)O)(2)]·2H(2)O}(n), the Cu(II) atom adopts an N(4)F(2)-octa-hedral coordination geometry with four pyridine N atoms in the equatorial sites and two F atoms in the axial sites. The di-3-pyridyl-methanone and hexa-fluoro-silicate ligands act as bidentate ligands, linking symmetry-related Cu(II) atoms. Water mol-ecules form O-H⋯O and O-H⋯F hydrogen bo...

متن کامل

Poly[[bis­(μ2-6-methyl­pyrazin-2-carboxyl­ato-κ3 N 1,O:N 4)copper(II)] dihydrate]

In the title compound, {[Cu(C(6)H(5)N(2)O(2))(2)]·2H(2)O}(n), the Cu(II) ion (site symmetry ) is coordinated by two N,O-bidentate ligands and two N-monodentate ligands in a distorted CuO(2)N(4) octa-hedral geometry. Each anion acts as a bridge between two cations, thus forming a two-dimensional polymeric network parallel to the ab plane. The packing is consolidated by O-H⋯O hydrogen bonds. One ...

متن کامل

Poly[[diaquadi-μ2-cyanido-bis­(μ2-pyrazine-2-carboxyl­ato)dicopper(I)copper(II)] dihydrate]

In the title compound, {[Cu(II)Cu(I) (2)(C(5)H(3)N(2)O(2))(2)(CN)(2)(H(2)O)(2)]·2H(2)O}(n), the Cu(II) atom lies on an inversion centre and is octa-hedrally coordinated by two N atoms and two O atoms from opposing pyrazine-2-carboxyl-ate (2-pac) ligands and two water O atoms. The Cu(I) atom has a triangular geometry, coordinated by one N atom and one C atom from two bridging cyanide ligands, an...

متن کامل

Poly[[μ2-1,3-bis­(imidazol-1-ylmeth­yl)benzene][μ2-2,2′-dihy­droxy-1,1′-methyl­enebis(naphthalene-3-carboxyl­ato)]zinc]

In the title compound, [Zn(C(23)H(14)O(6))(C(14)H(14)N(4))](n), the Zn(II) ion is four-coordinated in a distorted tetra-hedral geometry. The 1,3-bis-(imidazol-1-ylmeth-yl)benzene and 2,2'-dihy-droxy-1,1'-methyl-enebis(naphthalene-3-carboxy-l-ate) ligands con-nect the Zn(II) ions alternately in different directions, forming a layered structure parallel to the ac plane. Topological analysis revea...

متن کامل

Poly[[bis­[μ2-8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydro­pyrido[2,3-d]pyrimidine-6-carboxyl­ato]manganese(II)] dihydrate]

In the title compound, {[Mn(C(14)H(16)N(5)O(3))(2)]·2H(2)O}(n), the Mn(II) atom (site symmetry ) exhibits a distorted trans-MnN(2)O(4) octa-hedral geometry defined by two monodentate N-bonded and two bidentate O,O'-bonded 8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydro-pyrido[2,3-d]pyrimidine-6-carboxyl-ate anions. An N-H⋯O hydrogen bond is present in the crystal structure. The extended two-dimens...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 68  شماره 

صفحات  -

تاریخ انتشار 2012