Theoretical study of the absorption spectra of the sodium dimer

نویسنده

  • J. F. Babb
چکیده

Absorption of radiation from the sodium dimer molecular states correlating to Na(3s)-Na(3s) is investigated theoretically. Vibrational bound and continuum transitions from the singlet X Σg state to the first excited A Σu and B Πu states and from the triplet a Σu state to the first excited b Σg and c Πg states are studied quantum-mechanically. Theoretical and experimental data are used to characterize the molecular properties taking advantage of knowledge recently obtained from ab initio calculations, spectroscopy, and ultra-cold atom collision studies. The quantum-mechanical calculations are carried out for temperatures in the range from 500 to 3000 K and are compared with previous calculations and measurements where available. PACS numbers: 33.20.-t, 34.20.Mq, 52.25.Qt Typeset using REVTEX 1

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تاریخ انتشار 2013