Pd(II)/HPMoV-catalyzed direct oxidative coupling reaction of benzenes with olefins.
نویسندگان
چکیده
The direct aerobic coupling reaction of arenes with olefins was successfully achieved by the use of Pd(OAc)2/molybdovanadophosphoric acid (HPMoV) as a key catalyst under 1 atm of dioxygen. This catalytic system could be extended to the coupling reaction of various substituted benzenes with olefins such as acrylates, aclrolein, and ethylene through the direct aromatic C-H bond activation.
منابع مشابه
Direct oxidative coupling of benzenes with acrylonitriles to cinnamonitriles catalyzed by Pd(OAc)(2)/HPMoV/O(2) system.
A facile direct synthesis of cinnamonitriles from acrylonitriles and benzenes is successfully achieved by using Pd(OAc)(2)/HPMoV/O(2) catalyst system via the direct C-H bond activation of benzenes using molecular oxygen as a terminal oxidant.
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ورودعنوان ژورنال:
- Molecules
دوره 15 3 شماره
صفحات -
تاریخ انتشار 2010