A highly active cyclometallated iridium catalyst for the hydrogenation of imines.
نویسندگان
چکیده
A cyclometallated iridium complex containing an imino ligand has been shown to catalyse the hydrogenation of imines. The catalyst is highly active and selective for imino bonds, with a wide variety of imines being hydrogenated in less than 1 hour at a substrate/catalyst (S/C) ratio of 2000 at 20 bar H2 pressure and 75 °C.
منابع مشابه
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ورودعنوان ژورنال:
- Organic & biomolecular chemistry
دوره 11 40 شماره
صفحات -
تاریخ انتشار 2013