nd - m at . s of t ] 2 1 D ec 2 00 4 Spin - lattice NMR relaxation by anomalous translational diffusion

نویسنده

  • A. V. Anisimov
چکیده

A model-free theoretical framework for a phenomenological description of spinlattice relaxation by anomalous translational diffusion in inhomogeneous systems based on the fractional diffusion equation is developed. The dependence of the spinlattice relaxation time on the size of the pores in porous glass Vycor is experimentally obtained and found to agree well with our theoretical predictions. We obtain nonmonotonic behavior of the translational spin-lattice relaxation rate constant (it passes through a maximum ) with the variation of the parameter referring to the extent of inhomogeneity of the system.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Spin-lattice NMR relaxation by anomalous translational diffusion.

A model-free theoretical framework for a phenomenological description of spin-lattice relaxation by anomalous translational diffusion in inhomogeneous systems based on the fractional diffusion equation is developed. The dependence of the spin-lattice relaxation time on the size of the pores in porous glass Vycor is experimentally obtained and found to agree well with our theoretical predictions...

متن کامل

0 Fe b 20 04 Spin - lattice NMR relaxation by anomalous translational diffusion

A model-free theoretical framework for phenomenological description of spinlattice relaxation by anomalous translational diffusion in inhomogeneous systems based on the fractional diffusion equation is developed. The dependence of the spin-lattice relaxation time on the size of the pores in porous glass Vycor is experimentally obtained and found to agree well with theoretical predictions. We ob...

متن کامل

Cationic Self-diffusion in Solid Choline Perchlorate Studied by NMR

The H spin-lattice and spin-spin relaxation times, and the second moment of the 1 H NMR linewidth of choline Perchlorate, [(Cff^NCfFCHiOHJClC^, were measured in its highest-temperature solid phase, i. e. above 275 K. X-ray powder patterns taken at ca. 380 K revealed that in this phase the crystal has a CsCl-type cubic structure (a = 6.326(4) A and Z = 1). From *H NMR experiments it was found th...

متن کامل

Slow diffusion of macromolecular assemblies by a new pulsed field gradient NMR method.

The translational diffusion coefficient of an integral membrane protein/surfactant complex has been measured using a novel pulsed field gradient NMR method. In this new approach, the information about the localization of the molecules is temporarily stored in the form of longitudinal magnetization of isotopes with long spin-lattice relaxation times. This allows one to increase the duration of t...

متن کامل

4 A pr 2 00 9 Dynamics and transport of the Z 2 spin liquid : application to κ -

We describe neutron scattering, NMR relaxation, and thermal transport properties of Z2 spin liquids in two dimensions. Comparison to recent experiments on the spin S = 1/2 triangular lattice antiferromagnet in κ-(ET)2Cu2(CN)3 shows that this compound may realize a Z2 spin liquid. We argue that the topological ‘vison’ excitations dominate thermal transport, and that recent thermal conductivity e...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2004