Singlet delta oxygen production from a gas-solid reaction.
نویسندگان
چکیده
Spontaneous reactions between alkali metal or alkaline earth peroxides and hydrogen (deuterium) halide gases demonstrate the efficient production of singlet delta oxygen in a non-liquid medium. These reactions occur under ambient conditions without the need for any external energy source. The production of singlet delta oxygen was verified by direct emission spectroscopy at 1.27 microns with a calibrated optical multichannel analyzer. These reactions overcome the severe quenching problems encountered in liquid* phase reactions and the dangers/inconvenience ass6ciated with the use of basic hydrogen perokide for the chemical oxygen iodine laser (COIL). F) T5,lU ON STATEMENT A Approved for Public Release Distribution Unlimited
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ورودعنوان ژورنال:
- Angewandte Chemie
دوره 41 17 شماره
صفحات -
تاریخ انتشار 2002