Characteristics of Carbon Material Formation on SBA-15 and Ni-SBA-15 Templates by Acetylene Decomposition and Their Bioactivity Effects

نویسندگان

  • Hsiu-Mei Chiang
  • Kuan-Yu Cho
  • Li-Xuan Zeng
  • Hung-Lung Chiang
چکیده

Carbon spheres and tubes were formed from acetylene decomposition on SBA-15 and Ni-SBA-15 at 650-850 °C. At 650 °C, the decomposed carbons covered the surface of the support, and no carbon spheres and filament materials were formed. Carbon sphere formation occurred at 750 °C-850 °C; with diameters ranging from 0.8 μm-1.1 μm. For Ni-SBA-15, the diameters of the spheres and filaments were 0.8 μm and 62 nm, respectively, at 650 °C. At 750 °C, the diameter of the ball carbon materials ranged from 0.7 μm-0.8 μm, the diameter of the carbon tubes formed was 120-130 nm, and their pore diameter was 8.0 nm-11 nm. At 850 °C, the diameters of ball carbon materials and carbon tubes were similar to those of the materials at the formation temperature, 750 °C. Si, O and C were the main constituents of SBA-15; Ni-SBA-15 and carbon material formation supports. High-ring PAHs (such as BaP (five rings); IND (six rings); DBA (five rings) and B[ghi]P (six rings)) exist in carbon materials. SBA-15 revealed insignificant cytotoxicity, but Ni-SBA-15 inhibited the proliferation of human lung cancer cells (A549). Less inhibition on cell viability and reactive oxidative species (ROS) generation on A549 were determined for carbon material formation on the Ni-SBA-15 compared to the Ni-SBA-15.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Catalytic Steam Reforming of Toluene as a Model Compound of Biomass Gasification Tar Using Ni-CeO2/SBA-15 Catalysts

Nickel supported on SBA-15 doped with CeO2 catalysts (Ni-CeO2/SBA-15) was prepared, and used for steam reforming of toluene which was selected as a model compound of biomass gasification tar. A fixed-bed lab-scale set was designed and employed to evaluate the catalytic performances of the Ni-CeO2/SBA-15 catalysts. Experiments were performed to reveal the effects of several factors on the toluen...

متن کامل

A Comparison Study on Carbon Dioxide Reforming of Methane Over Ni Catalysts Supported on Mesoporous SBA-15, MCM-41, KIT-6 and γ-Al2O3

The activity of Ni supported on mesoporous SBA-15, MCM-41, KIT-6, and a sol-gel prepared Ni/γAl2O3, for catalysing methane dry reforming was investigated. The chemical and physical characteristics of the catalysts before and after catalytic testing were investigated using X-Ray diffraction, X-ray Photoemission Spectroscopy, Transmission Electron Microscopy, Scanning Electron Microscopy / Energy...

متن کامل

Synthesis and Characterization of Amine-modified Mesoporous SBA-15 for Carbon Dioxide Sequestration at High Pressure and Room Temperature (RESEARCH NOTE)

Amine-modified mesoporous SBA-15 adsorbent has been prepared by impregnation method using tetraethylenepentamine. The samples of this modified SBA-15 have been characterized by small angle X-ray scattering (SAXS), Scanning electron microscopy (SEM), Nitrogen adsorption-desorption isotherm and FT-IR. The adsorption capacity of CO2 on unmodified and modified samples were measured at high pressure...

متن کامل

Preparation of Ni-based metal monolithic catalysts and a study of their performance in methane reforming with CO2.

A series of Ni/SBA-15/Al(2)O(3)/FeCrAl metal monolithic catalysts with Ni loadings varying between 3 % and 16 % were prepared, and their structure was characterized by various techniques. The catalytic activity of the catalyst for methane reforming with CO(2) leading to synthesis gas was evaluated using a fixed-bed reactor. The results indicate good catalytic activity of the Ni/SBA-15/Al(2)O(3)...

متن کامل

Preparation and physical characterization of calcium sulfate cement/silica-based mesoporous material composites for controlled release of BMP-2

As a commonly used implant material, calcium sulfate cement (CSC), has some shortcomings, including low compressive strength, weak osteoinduction capability, and rapid degradation. In this study, silica-based mesoporous materials such as SBA-15 were synthesized and combined with CSC to prepare CSC/SBA-15 composites. The properties of SBA-15 were characterized by X-ray diffraction, transmission ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 9  شماره 

صفحات  -

تاریخ انتشار 2016