Kinetics of the Oxidation of N-Aminopiperidine with Chloramine
نویسندگان
چکیده
The kinetics of the oxidation of N-aminopiperidine with chloramine was studied at different temperatures, with variable concentrations of the two reactants and at a pH ranging between 12 and 13.5. The reaction showed to be involving two steps: the first corresponded to the formation of a diazene intermediate, the second to the evolution of this intermediate into numerous compounds within a complex reactional chain. The rate law of the first step was determined by the Ostwald method and ha l-0 03 97 53 3, v er si on 1 22 J un 2 00 9 Author manuscript, published in "Kinetics and Catalysis 50, 1 (2009) 103-111"
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