N′-(5-Bromo-2-hydroxy-3-methoxybenzylidene)isonicotinohydrazide
نویسندگان
چکیده
The title compound, C(14)H(12)BrN(3)O(3), was prepared by reaction of 5-bromo-3-methoxy-salicylaldehyde and isonicotinohydrazide in methanol. The mol-ecule is not planar and adopts a trans configuration with respect to the C=N bond. There is an intra-molecular O-H⋯N hydrogen bond in the mol-ecule. The dihedral angle between the benzene and pyridine rings is 12.2 (2)°. In the crystal structure, mol-ecules are linked through inter-molecular N-H⋯N hydrogen bonds, forming chains running along the c-axis direction.
منابع مشابه
N′-(2-Hydroxy-4-methoxybenzylidene)isonicotinohydrazide
The title compound, C(14)H(13)N(3)O(3), was synthesized by the condensation reaction of 2-hydr-oxy-4-methoxy-benzaldehyde with isonicotinohydrazide in a methanol solution. The mol-ecule of the compound displays a trans configuration with respect to the C=N and C-N bonds. The dihedral angle between the benzene and the pyridine rings is 27.3 (2)°. In the crystal, mol-ecules are linked by N-H⋯N in...
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