Crystal structure of (Z)-2-hydroxy-4-methyl-N′-(4-oxo-1,3-thiazolidin-2-ylidene)benzohydrazide trihydrate
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چکیده
In the title compound, C11H11N3O3S·3H2O, the non-H atoms of the main mol-ecule are approximately planar, with an r.m.s. deviation of 0.030 Å. There is a bifurcated intra-molecular N-H⋯(O,S) hydrogen bond present forming S(6) and S(5) ring motifs. In the crystal, O-H⋯O and N-H⋯O hydrogen bonds link the molecules into a three-dimensional network.
منابع مشابه
Crystal structure of (Z)-2-hydroxy-N′-(4-oxo-1,3-thiazolidin-2-ylidene)benzohydrazide
In the title compound, C10H9N3O3S, the five-membered ring adopts a slightly twisted conformation about the Cm-S (m = methyl-ene) bond. The dihedral angle between this ring and the benzene ring is 7.99 (9)°. A bifurcated intra-molecular N-H⋯(O,S) hydrogen bond helps to establish the near planar conformation of the mol-ecule. In the crystal, mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen bonds...
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In the title compound, C(4)H(5)N(3)S, the tdihydrothiazole ring is almost planar, the maximum and minimum deviations being 0.188 (2) Å and 0.042 (3) Å, respectively. The crystal structure involves intermolecular N-H⋯N hydrogen bonds.
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