Catalytic Activity of Pd/Cu Random Alloy Nanoparticles for Oxygen Reduction.

Correction to "Catalytic Activity of Pd/Cu Random Alloy Nanoparticles for Oxygen Reduction".

Tuning the Oxygen Reduction Activity of Pd Shell Nanoparticles with Random Alloy Cores

Pd-based nanoparticles are promising candidates for non-Pt catalysts of the oxygen reduction reaction (ORR). Trends in ORR activity of Pd/Cu-alloy-core@Pd-shell nanoparticles are studied by calculating the oxygen binding energy on the Pd surface with different Cu compositions in the alloy core. Density functional theory calculations show that several properties of the nanoparticle surface, incl...

Core-shell Au@Pd nanoparticles with enhanced catalytic activity for oxygen reduction reaction via core-shell Au@Ag/Pd constructions

Core-shell nanoparticles often exhibit improved catalytic properties due to the lattice strain created in these core-shell particles. Herein, we demonstrate the synthesis of core-shell Au@Pd nanoparticles from their core-shell Au@Ag/Pd parents. This strategy begins with the preparation of core-shell Au@Ag nanoparticles in an organic solvent. Then, the pure Ag shells are converted into the shell...

Cage-bell Pt-Pd nanostructures with enhanced catalytic properties and superior methanol tolerance for oxygen reduction reaction.

Precisely tailoring the structure and fully making use of the components of nanoparticles are effective to enhance their catalytic performance for a given reaction. We herein demonstrate the design of cage-bell structured Pt-Pd nanoparticles, where a Pd shell is deliberately selected to enhance the catalytic property and methanol tolerance of Pt for oxygen reduction reaction. This strategy star...

Pt Monolayer Electrocatalyst for Oxygen Reduction Reaction on Pd-Cu Alloy: First-Principles Investigation

First principles approach is used to examine geometric and electronic structure of the catalyst concept aimed to improve activity and utilization of precious Pt metal for oxygen reduction reaction in fuel cells. The Pt monolayers on Pd skin and Pd1−xCux inner core for various compositions x were examined by building the appropriate models starting from Pd-Cu solid solution. We provided a detail...