Supramolecular Assemblies: Dendrimers, Linear Arrays, and Polypseudorotaxanes
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منابع مشابه
Supramolecular Disassembly of Facially Amphiphilic Dendrimer Assemblies in Response to Physical, Chemical, and Biological Stimuli
CONSPECTUS: Supramolecular assemblies formed from spontaneous self-assembly of amphiphilic macromolecules are explored as biomimetic architectures and for applications in areas such as sensing, drug delivery, and diagnostics. Macromolecular assemblies are usually preferred, compared with their simpler small molecule counterparts, due to their low critical aggregate concentrations (CAC) and high...
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We report herein the concept of using a supramolecular platform on which dendrimers can be immobilized to result in tunneling junctions formed from assemblies with well-defined structures. In this way, the rectification can be controlled by changing only the chemical structure of the termini of the dendrimers, while minimizing the changes of the whole supramolecular assemblies. This method make...
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Multiple photosynthetic reaction centres have successfully been constructed using supramolecular complexes of zinc porphyrin dendrimers [D(ZnP)(n): n = 4, 8, 16] with fulleropyrrolidine bearing a pyridine ligand (C(60)py). Efficient energy migration occurs completely between the ZnP units of dendrimers prior to the electron transfer with increasing the generation of dendrimers to attain an extr...
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Host-stabilized charge-transfer (CT) interactions and supramolecular assemblies built with these interactions are described. A variety of supramolecular assemblies including polyrotaxanes, molecular necklaces, and rotaxane dendrimers were synthesized through the intramolecular or intermolecular host-stabilized CT complex formation using cucurbit[8]uril (CB[8]) and D-A molecules having both elec...
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The association of the arene ruthenium metallacycle [Ru4(p-cymene)4(bpe)2(donq)2][DOS]4 (bpe = 1,2-bis(4-pyridyl)ethylene, donq = 5,8-dioxydo-1,4-naphtoquinonato, DOS = dodecyl sulfate) with pyrenyl-functionalized poly(arylester) dendrimers bearing cyanobiphenyl end-groups is reported. The supramolecular dendritic systems display mesomorphic properties as revealed by polarized optical microscop...
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