Oxidative group transfer to Co(I) affords a terminal Co(III) imido complex.
نویسندگان
چکیده
The synthesis of the first terminal imido complex of cobalt, [PhBP3]CoN-p-tolyl, is reported. Its synthesis proceeds by oxidative group transfer from cobalt(I) upon addition of tolyl azide at room temperature. This species and a related eta1-diazoalkane adduct have been structurally characterized. The diamagnetic imido complex [PhBP3]CoN-p-tolyl reacts with CO to liberate isocyanate and the cobalt(I) dicarbonyl complex [PhBP3]Co(CO)2.
منابع مشابه
Crystal Structure of Trans- [bis(2,5-dichlorophenylcyanamido) {N,N′-propanediylbis(2,3-butadien-2-imine-3-oxime)} Cobalt(III)], trans-[Co((DO)(DOH)pn)(2,5-Cl2pcyd)2]
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ورودعنوان ژورنال:
- Journal of the American Chemical Society
دوره 124 38 شماره
صفحات -
تاریخ انتشار 2002