Unraveling the mechanism of molecular doping in organic semiconductors.

نویسندگان

  • Alexander Mityashin
  • Yoann Olivier
  • Tanguy Van Regemorter
  • Cedric Rolin
  • Stijn Verlaak
  • Nicolas G Martinelli
  • David Beljonne
  • Jérôme Cornil
  • Jan Genoe
  • Paul Heremans
چکیده

The mechanism by which molecular dopants donate free charge carriers to the host organic semiconductor is investigated and is found to be quite different from the one in inorganic semiconductors. In organics, a strong correlation between the doping concentration and its charge donation efficiency is demonstrated. Moreover, there is a threshold doping level below which doping simply has no electrical effect.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Scattering mechanism of nonmagnetic phase on nano diluted magnetic semiconductors (DMS)

This paper shows the scattering mechanism at diluted magneticsemiconductors. The doped magnetic atom produces a scattering potential due to becoupled of itinerant carrier spin of host material with magnetic momentum of the dopedmagnetic atom. Formulas of scattering event were rewritten by the plane waveexpansion and then the electron mobility of DMS was calculated. Calculations showKondo effect...

متن کامل

Field Dependent Charge Carrier Transport for Organic Semiconductors at the Time of Flight Configuration

In this paper, we used the time-of-flight (TOF) of a charge packet, that injected by a voltage pulse to calculate the drift velocity and mobility of holes in organic semiconducting polymers. The technique consists in applying a voltage to the anode and calculating the time delay in the appearance of the injected carriers at the other contact. The method is a simple way to determine the charge t...

متن کامل

Molecular doping in organic semiconductors: fully solution-processed, vacuum-free doping with metalorganic complexes in an orthogonal solvent

Chemical doping in p-conjugated organic semiconductors, which involves a redox reaction between a host p-conjugated material and a dopant, is achieved by either co-evaporation, co-dissolved solution, or exposure to a dopant gas. Here, we demonstrate a new route for molecular doping; a thiophene-based semiconducting polymer film can be doped with dopants dispersed in an orthogonal solvent. An in...

متن کامل

Hole doping by molecular oxygen in organic semiconductors: Band-structure calculations

The sensitive effect of O2 adsorption on the electronic properties of organic semiconductors is investigated by band structure calculation. O2 can actually p-dope the host materials even without illumination, i.e., a ground state property, in the circumstance of saturated coverage. Due to hybridization between O2 and polymer, Fermi level of the oxygenated system is pinned at the nearly half-fil...

متن کامل

Electrical doping: the impact on interfaces of π-conjugated molecular films

Abstract Organic–metal and organic–organic interfaces play crucial roles in charge injection in, and transport through, organic thin film devices. Their electronic structure, chemical properties and electrical behaviour must be fully characterized and understood if engineering and control of organic devices are to reach the levels attained for inorganic semiconductor devices. Recent fundamental...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Advanced materials

دوره 24 12  شماره 

صفحات  -

تاریخ انتشار 2012