{Ni4O4} Cluster Complex to Enhance the Reductive Photocurrent Response on Silicon Nanowire Photocathodes

نویسندگان

  • Yatin J. Mange
  • Soundarrajan Chandrasekaran
  • Nathan Hollingsworth
  • Nicolas H. Voelcker
  • Ivan P. Parkin
  • Thomas Nann
  • Thomas J. Macdonald
چکیده

Metal organic {Ni₄O₄} clusters, known oxidation catalysts, have been shown to provide a valuable route in increasing the photocurrent response on silicon nanowire (SiNW) photocathodes. {Ni₄O₄} clusters have been paired with SiNWs to form a new photocathode composite for water splitting. Under AM1.5 conditions, the combination of {Ni₄O₄} clusters with SiNWs gave a current density of -16 mA/cm², which corresponds to an increase in current density of 60% when compared to bare SiNWs. The composite electrode was fully characterised and shown to be an efficient and stable photocathode for water splitting.

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عنوان ژورنال:

دوره 7  شماره 

صفحات  -

تاریخ انتشار 2017