Novel chiral "calixsalen" macrocycle and chiral robson-type macrocyclic complexes.
نویسندگان
چکیده
A family of novel chiral "calixsalen" Schiff base macrocycles R,R-H(3)L4, R,R-H(3)L5, containing three chiral diamino moieties were synthesized by an efficient self-assembly and characterized by (1)H and (13)C NMR, mass spectrometry, and X-ray diffraction. The systematic synthesis, structure, and coordination properties of the [2 + 2] and [3 + 3] Robson-type Schiff base macrocyclic mono-, di-, tri-, and tetranuclear metal complexes were explored.
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ورودعنوان ژورنال:
- Inorganic chemistry
دوره 44 2 شماره
صفحات -
تاریخ انتشار 2005