Hydration of epoxides on [CoIII salen)] encapsulated in silica-based nanoreactors.
نویسندگان
چکیده
منابع مشابه
An achiral manganese salen catalyst encapsulated in a peptidic phosphonate homochiral solid for the enantioselective formation of diols by consecutive epoxidation and hydration reactions.
An insoluble, porous, amorphous, homochiral material based on a polypeptide titanium-phosphonate scaffold with an encapsulated achiral Mn(III)-salen was prepared and characterized. Consecutive epoxidation and hydration of styrene and its derivatives by aqueous hypochlorite in THF showed the highly enantioselective (>99%) formation of styrene diol derivatives.
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ورودعنوان ژورنال:
- Angewandte Chemie
دوره 51 46 شماره
صفحات -
تاریخ انتشار 2012