'Sergeants-and-Corporals' principle in chiral induction at an interface.
نویسندگان
چکیده
Self-assembly of an achiral porphyrin at the interface between a chiral solvent and an atomically flat substrate renders the monolayer chiral, and a non-racemic solvent can even overrule the intrinsic expression of chirality in the self-assembly of chiral molecules.
منابع مشابه
Complex Chiral Induction Processes at the Solution/Solid Interface
Two-dimensional supramolecular chirality is often achieved by confining molecules against a solid surface. The sergeants-soldiers principle is a popular strategy to fabricate chiral surfaces using predominantly achiral molecules. In this method, achiral molecules (the soldiers) are forced to assemble in a chiral fashion by mixing them with a small percentage of structurally similar chiral molec...
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 68 شماره
صفحات -
تاریخ انتشار 2013