A novel, rigid diphosphine with an active NHC spacer; di- and trinuclear complexes of d10 coinage metals.
نویسندگان
چکیده
A novel N,N'-diphosphanyl-imidazol-2-ylidene acts as a stable, hybrid PC(NHC)P ligand for M2 or linear M3 (M = Cu, Ag, Au) arrays with metallophilic interactions.
منابع مشابه
Well-defined coinage metal transfer agents for the synthesis of NHC-based nickel, rhodium and palladium macrocycles†
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متن کاملDiverse reactivity of a tricoordinate organoboron L2PhB: (L = oxazol-2-ylidene) towards alkali metal, group 9 metal, and coinage metal precursors† †Electronic supplementary information (ESI) available: Experimental and calculation details, and crystallographic information for 2, 3, 4, 6, 8. CCDC 1038665, 1038666, 1038667, 1011534, and 1011533. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc00404g Click here for additional data file. Click here for additional data file.
This journal is © The Royal Society of C of a tricoordinate organoboron L2PhB: (L 1⁄4 oxazol-2-ylidene) towards alkali metal, group 9 metal, and coinage metal precursors† Lingbing Kong, Rakesh Ganguly, Yongxin Li and Rei Kinjo* The reactivity of a tricoordinate organoboron L2PhB: (L1⁄4 oxazol-2-ylidene) 1 towards metal precursors and its coordination chemistry were comprehensively studied. Whil...
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 1 شماره
صفحات -
تاریخ انتشار 2014