Tricarbon­yl(η6-flavone)chromium(0)

نویسندگان

  • Johannes H. van Tonder
  • Barend C. B. Bezuidenhoudt
  • J. Marthinus Janse van Rensburg
چکیده

In the title compound, [Cr(C(15)H(10)O(2))(CO)(3)], the Cr(CO)(3) unit exhibits a three-legged piano-stool conformation. The chromium metal centre is coordinated by the phenyl ring of the flavone ligand [Cr-(phenyl centroid) distance = 1.709 (1) Å]. The ligand is approximately planar, the dihedral angles between the γ-pyrone ring and the phenyl ring and between the γ-pyrone and the phenyl-ene ring being 2.91 (5) and 3.90 (5)°, respectively. The mol-ecular packing shows π-π stacking between the flavone ligands of neighbouring mol-ecules.

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عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009