A PdAg bimetallic nanocatalyst for selective reductive amination of nitroarenes.
نویسندگان
چکیده
Herein we have identified an optimal catalyst, Pd1Ag1.7, for the tandem reductive amination between nitroarenes and aldehydes (selectivity > 93%). Key to the success is the ability to control the compositions of the investigational Pd1-xAgx (x = 0-1) catalysts, as well as the clear composition dependent activity/selectivity trend observed in this study. This catalyst features a wide substrate scope, excellent recyclability, activity and selectivity under ambient conditions.
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 61 شماره
صفحات -
تاریخ انتشار 2013