The Jahn-Teller and Related Effects in the Silver Trimer, Part II: Vibrational Analysis of the ÃE ′′-X̃2E ′ Electronic Transition
نویسندگان
چکیده
The laser excited, jet-cooled Ã2E′′ − X̃2E′ electronic spectrum of the silver trimer yields detailed information about its Ãand X̃-state vibronic structure. Following extensive parameter fitting, the absorption and emission spectra are simulated and the bands are assigned. The JahnTeller analysis includes both linear and quadratic coupling terms, considered simultaneously with spin-orbit coupling. The spin-orbit splitting is shown to be largely quenched in both the à and X̃ electronic states. The Jahn-Teller analysis of the à and X̃ vibronic structures reveals the distortion of their corresponding potential energy surfaces.
منابع مشابه
The Jahn-Teller and Related Effects in the Cyclopentadienyl Radical, Part II: Vibrational Analysis of the Ã2A′′
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