(Methoxycarbonyl)hydrazinium chloride monohydrate
نویسندگان
چکیده
In the title compound, C(2)H(7)N(2)O(2) (+)·Cl(-)·H(2)O, the non-H atoms of the cation are approximately coplanar. The organic cations, chloride ions and water mol-ecules are linked into a two-dimensional network parallel to the bc plane by N-H⋯O, N-H⋯Cl and O-H⋯Cl hydrogen bonds.
منابع مشابه
Poly[hydrazin-1-ium [diaquabis(μ4-pyridazine-3,6-dicarboxylato)trilithate] monohydrate]
The structure of the title compound, {(N(2)H(5))[Li(3)(C(6)H(2)N(2)O(4))(2)(H(2)O)(2)]·H(2)O}(n), is composed of mol-ecular dimers, each built up of two symmetry-related Li(I) ions with distorted trigonal-bipyramidal coordinations bridged by two deprotonated ligand mol-ecules via their N,O-bonding sites. Doubly solvated Li(I) ions with a distorted tetra-hedral geometry link adjacent dimers, for...
متن کامل2-(4-Chlorobenzoyl)-1-(diaminomethylene)hydrazinium chloride monohydrate
In the cation of the title compound, C(8)H(10)ClN(4)O(+)·Cl(-)·H(2)O, the guanidinium group is planar (maximum deviation = 0.0001 Å) and nearly perpendicular to carboxamide group, making a dihedral angle of 87.0 (3)°. The N atoms of the guanidine fragment have a planar trigonal configuration and the N atom of the carboxamide group adopts a pyramidal configuration. In the crystal structure, inte...
متن کامل2-(4-Sulfamoylphenyl)hydrazin-1-ium chloride
The hydrazinium residue in the cation of the title salt, C(6)H(10)N(3)O(2)S(+)·Cl(-), is twisted out of the plane of the benzene ring to which it is attached [N-N-C-C torsion angle = 25.9 (2)°] and the amino group is almost perpendicular to the benzene ring [N-S-C-C torsion angle = 88.71 (16)°]. In the crystal, the cations are linked by N-H⋯O hydrogen bonds and π-π inter-actions [ring centroid ...
متن کاملA new reagent for selective reduction of nitro group
The nitro group in aromatic nitro compounds containing reducible substituents such as methyl, carboxylic acids and phenols, and halogens are selectively and rapidly reduced at room temperature to the corresponding amines in good yield by employing hydrazine glyoxylate in the presence of zinc powder or magnesium powder. It has been observed that hydrazine glyoxylate is more effective than hydraz...
متن کاملHigh-nitrogen Compounds for Use in Low-erosivity Gun Propellants
Nitrogen rich compounds are suitable as ingredients in low smoke propellant charges. Several high-N energetic materials are presented which are based on tetrazoles. Tetrazoles are an unique class of compounds, since they combine a high nitrogen content and a high heat of formation with good thermal and kinetic stabilities due to their aromatic ring system. The reaction of 5azidotetrazole with h...
متن کامل