Yielding and flow in adhesive and nonadhesive concentrated emulsions.
نویسندگان
چکیده
The nonlinear rheological response of soft glassy materials is addressed experimentally by focusing on concentrated emulsions where interdroplet attraction is tuned through varying the surfactant content. Velocity profiles are recorded using ultrasonic velocimetry simultaneously to global rheological data in the Couette geometry. Our data show that nonadhesive and adhesive emulsions have radically different flow behaviors in the vicinity of yielding: while the flow remains homogeneous in the nonadhesive emulsion and the Herschel-Bulkley model for a yield stress fluid describes the data very accurately, the adhesive system displays shear localization and does not follow a simple constitutive equation, suggesting that the mechanisms involved in yielding transitions are not universal.
منابع مشابه
Microscale rheology of a soft glassy material close to yielding.
Using confocal microscopy, we study the flow of a model soft glassy material: a concentrated emulsion. We demonstrate the micro-macro link between in situ measured movements of droplets during the flow and the macroscopic rheological response of a concentrated emulsion, in the form of scaling relationships connecting the rheological "fluidity" with local standard deviation of the strain-rate te...
متن کاملType 1 fimbriae of Salmonella enterica serovar Typhimurium bind to enterocytes and contribute to colonization of swine in vivo.
Salmonella enterica serovar Typhimurium strain 798 is a clinical isolate from a pig and is known to be able to cause persistent, asymptomatic infections. This strain also is known to exist in two phenotypes (adhesive and nonadhesive to enterocytes) and can switch between the two phenotypes at a rate consistent with phase variation. Cells in the adhesive phenotype are more readily phagocytosed b...
متن کاملYielding and Rearrangements in Disordered Emulsions
We use diffusing-wave spectroscopy to measure the motion of droplets in concentrated emulsions subjected to a periodic shear strain. The strain gives rise to periodic echoes in the correlation function which decay with increasing strain amplitude. For a given strain amplitude, the decay of the echoes implies that a finite fraction of the emulsion droplets never rearranges under periodic strain ...
متن کاملRheology on the Way from Dilute to Concentrated Emulsions
The short review presents the analysis of the consecutive evolution of the rheology of emulsions starting from dilute systems (behavior of an individual liquid droplet in a continuous liquid phase) till the highly concentrated emulsions, in which droplets loose their spherical shape and become polygons. Along with the increase of the internal phase concentration, this is the transition from a s...
متن کاملFlow characteristics of concentrated emulsions of very viscous oil in water
This paper advances ideas and presents experiments on the flow characteristics of concentrated emulsions of Venezuelan bitumen in water plus surfactant. These emulsions are studied under a variety of flow conditions, namely between rotating cylinders, in a colloid mill and in pipes. The ideas advanced here concern the modeling of the highly viscous bitumen drops as solid spheres and their fract...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Physical review letters
دوره 96 13 شماره
صفحات -
تاریخ انتشار 2006