A nanoporous oxide interlayer makes a better Pt catalyst on a metallic substrate: Nanoflowers on a nanotube bed
نویسندگان
چکیده
To improve the contact between platinum catalyst and titanium substrate, a layer of TiO 2 nanotube arrays has been synthesized before depositing Pt nanoflowers by pulse electrodeposition. Dramatic improvements in electrocatalytic activity (3×) and stability (60×) for methanol oxidation were found, suggesting promising applications in direct methanol fuel cells. The 3× and 60× improvements persist for Pt/Pd catalysts used to overcome the CO poisoning problem.
منابع مشابه
Introducing Pt/ZnO as a new non carbon substrate electro catalyst for oxygen reduction reaction at low temperature acidic fuel cells
Gas diffusion electrode was used for providing better conditions in fuel cell systems for oxygen reduction reaction (ORR). Because the slow kinetics of the oxygen reduction reaction at the proton exchange membrane fuel cell cathode restricts fuel cell efficiency. To this end, researchers have used platinum-coated carbon. In the present study, due to the reduction of carbon corrosion, Zinc oxide...
متن کاملIntroducing Pt/ZnO as a new non carbon substrate electro catalyst for oxygen reduction reaction at low temperature acidic fuel cells
Gas diffusion electrode was used for providing better conditions in fuel cell systems for oxygen reduction reaction (ORR). Because the slow kinetics of the oxygen reduction reaction at the proton exchange membrane fuel cell cathode restricts fuel cell efficiency. To this end, researchers have used platinum-coated carbon. In the present study, due to the reduction of carbon corrosion, Zinc oxide...
متن کاملEffect of Pt on Zn-Free Cu-Al Catalysts for Methanol Steam Reforming to Produce Hydrogen
Steam reforming of methanol can be considered as an attractive reaction aiming at hydrogen production for PEM fuel cells. Although Cu/Al-contained catalysts are considerably evaluated in this reaction, further evaluation is essential to evaluate the impact of some promoters like Pt in order to find a comprehensively optimized catalyst. Pt promoter is employed with different methods in this ...
متن کاملFacile Synthesis of Nanoporous Pt-Y alloy with Enhanced Electrocatalytic Activity and Durability
Recently, Pt-Y alloy has displayed an excellent electrocatalytic activity for oxygen reduction reaction (ORR), and is regarded as a promising cathode catalyst for fuel cells. However, the bulk production of nanoscaled Pt-Y alloy with outstanding catalytic performance remains a great challenge. Here, we address the challenge through a simple dealloying method to synthesize nanoporous Pt-Y alloy ...
متن کاملHighly ordered TiN nanotube arrays as counter electrodes for dye-sensitized solar cells.
TiN nanotube arrays, prepared by the anodization of metallic Ti foil substrate and subsequent simple nitridation in an ammonia atmosphere, were investigated as low-cost counter electrodes in dye-sensitized solar cells for the first time. It is found that the highly ordered TiN nanotube arrays on the metallic Ti foil substrate show an excellent performance, comparable with typical Pt counter ele...
متن کامل