Avoiding problem reactions at the ferrocenyl-alkyne motif: a convenient synthesis of model, redox-active complexes for molecular electronics.
نویسندگان
چکیده
A much improved route to 1,1'-bis(arylethynyl)ferrocenes comprising accessible thiolates on the aryl ring is reported. Unanticipated reactions between AcCl, TBAF-BBr3 and ferrocenyl-alkynes are also discussed, offering a rationale for previous synthetic difficulties.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 43 41 شماره
صفحات -
تاریخ انتشار 2014