cis-Chlorido(methylamine)bis(propane-1,3-diamine)cobalt(III) dichloride monohydrate
نویسندگان
چکیده
In the title compound, [CoCl(CH5N)(C3H10N2)2]Cl2·H2O, the Co(III) ion has an octa-hedral coordination environment and is surrounded by four N atoms of two propane-1,3-diamine ligands in the equatorial plane, with another N atom of the methylamine ligand and a Cl atom occupying the axial positions. The crystal packing is stabilized by inter-molecular N-H⋯O, N-H⋯Cl, and O-H⋯Cl inter-actions, generating a three-dimensional network.
منابع مشابه
cis-Chlorido(ethylamine)bis(propane-1,3-diamine)cobalt(III) dichloride
In the title compound, [CoCl(C2H7N)(C3H10N2)2]Cl2, the Co(III) ion has a distorted octa-hedral coordination environment and is surrounded by four N atoms in the equatorial plane, with the other N and Cl atoms occupying the axial positions. The crystal packing is stabilized by N-H⋯Cl hydrogen bonds, forming a layered arrangement parallel to (1-10).
متن کاملcis-Bromido(methylamine)bis(propane-1,3-diamine)cobalt(III) dibromide
In the title compound, [CoBr(CH5N)(C3H10N2)2]Br2, the cobalt(III) ion has a distorted octa-hedral coordination environment and is surrounded by four N atoms in the equatorial plane, with an additional N atom and the Br atom occupying the axial positions. In the crystal, the complex cation and the two counter anions are linked via N-H⋯Br and C-H⋯Br hydrogen bonds, forming a three-dimensional net...
متن کاملDiaqua[N,N′-bis(2-pyridylmethylene)propane-1,3-diamine]manganese(II) dibromide–aquabromido[N,N′-bis(2-pyridylmethylene)propane-1,3-diamine]manganese(II) bromide–dibromido[N,N′-bis(2-pyridylmethylene)propane-1,3-diamine]manganese(II) (1/2/1)
There are three different Mn(II) complexes in the asymmetric unit of the title compound, [Mn(C(15)H(16)N(4))(H(2)O)(2)]Br(2)·2{[MnBr(C(15)H(16)N(4))(H(2)O)]Br}·[MnBr(2)(C(15)H(16)N(4))]. In the neutral complex, the Mn(2+) ion is six-coordinated in a distorted octa-hedral environment by four N atoms of the tetra-dentate ligand N,N'-bis-(2-pyridylmethyl-ene)propane-1,3-diamine (bppd) and two brom...
متن کاملcatena-Poly[[bis(methanol-κO)bis(thiocyanato-κN)cobalt(II)]-μ-1,3-bis(pyridin-4-yl)propane-κ2 N,N′]
The asymmetric unit of the title compound, [Co(NCS)(2)(C(13)H(14)N(2))(CH(3)OH)(2)], consists of one cobalt(II) cation located on a center of inversion, one half of a 1,3-bis-(pyridin-4-yl)propane ligand located on a twofold rotation axis, as well as one thio-cyanate anion and one methanol mol-ecule in general positions. The cobalt(II) cation is coordinated by two terminal N-bonded thio-cyanate...
متن کاملcatena-Poly[cadmium-μ-[1,3-bis(imidazol-1-yl)propane]-di-μ-chlorido]
The title complex, [CdCl(2)(C(9)H(12)N(4))](n), is characterized by the formation of a zigzag chain structure parallel to [001]. In the chain, the Cd(2+) cation is coordinated by four bridging Cl(-) ligands in equatorial positions and two N atoms from symmetry-related and likewise bridging 1,3-bis-(imidazol-1-yl)propane ligands in axial positions, forming a distorted CdCl(4)N(2) octa-hedron.
متن کامل