Chloridobis[N′-(2-methoxybenzylidene)-4-nitrobenzohydrazidato-κ2 O,N′](4-methylpyridine-κN)cobalt(III)
نویسندگان
چکیده
In the title complex, [Co(C(15)H(12)N(3)O(4))(2)Cl(C(6)H(7)N)], the Co(III) ion is coordinated by two N atoms and two O atoms from two deprotonated Schiff base ligands, one N atom from a 4-methyl-pyridine ligand and one Cl atom, forming a distorted octa-hedral geometry. The Co(III) ion is displaced by 0.038 (2) Å from the equatorial plane towards the axial Cl atom.
منابع مشابه
Chloridobis(dimethylglyoximato-κ2 N,N′)(4-methylpyridine-κN)cobalt(III) hemihydrate
In the title complex, [Co(C(4)H(7)N(2)O(2))(2)Cl(C(6)H(7)N)]·0.5H(2)O, the central Co(III) ion, chelated by four N atoms of the two bidenate glyoximate ligands, exhibits a slightly distorted octa-hedral geometry. The axial positions are occupied by a chloride ion and the 4-methyl-pyridine N atom. Inter-molecular O-H⋯O hydrogen bonds link the mol-ecules in the crystal via the water mol-ecules, w...
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