N,S-Dimethyldithiocarbamyl oxalates as precursors for determining kinetic parameters for oxyacyl radicals.
نویسندگان
چکیده
N,S-Dimethyldithiocarbamyl oxalates (e.g.6, 10) are novel, readily prepared precursors to alkyloxyacyl radicals 1 that are more suitable for kinetic studies than existing precursors; 10 has allowed the determination of accurate rate data for the cyclization of the butenyloxyacyl radical 5 (kc = 1.2 × 10(7) s(-1) at 21 °C).
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 81 شماره
صفحات -
تاریخ انتشار 2014