[2,6-Bis(diphenylphosphanyloxy)phenyl-κ3 P,C 1,P′]hydroxidonickel(II)
نویسندگان
چکیده
The mol-ecule of the title complex, [Ni(C(30)H(23)O(2)P(2))(OH)], adopts a slightly distorted square-planar geometry around Ni(II) defined by the coordination of the two mutually trans P atoms, the Csp(2) atom of the pincer ligand and the O atom of the hydroxide ligand. The largest distortions from ideal geometry are reflected in the smaller than usual P-Ni-P [163.95 (3)°] and P-Ni-C [82.06 (6)°] angles. The OH ligand does not form intra- or inter-molecular hydrogen bonds.
منابع مشابه
{2,6-Bis[(diphenylphosphanyl)oxy]phenyl-κ3 P,C 1,P′}iodidonickel(II)
In the title complex, [Ni(C(30)H(23)O(2)P(2))I], the divalent Ni atom is coordinated by two P atoms and one C atom from the 1,3-bis-[(diphenyl-phosphan-yl)-oxy]benzene ligand; the distorted square-planar geometry is completed by an iodide ligand. The largest distortions from ideal square-planar geometry are reflected in the P-Ni-P angle of 164.20 (2)° and the P-Ni-C angles of 82.09 (6) and 82.1...
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