Chloridobis(ethane-1,2-diamine)(4-methylaniline)cobalt(III) dichloride monohydrate
نویسندگان
چکیده
In the title compound, [CoCl(C(2)H(8)N(2))(2)(C(7)H(9)N)]Cl(2)·H(2)O, the Co(III) ion has a distorted octa-hedral coordination environment and is surrounded by four N atoms in an equatorial plane, with the other N and Cl atoms occupying the axial positions. The crystal packing is stabilized by N-H⋯O, N-H⋯Cl and O-H⋯Cl inter-actions.
منابع مشابه
(Benzylamine)chloridobis(ethane-1,2-diamine)cobalt(III) dichloride hemihydrate
In the title compound, [CoCl(C(2)H(8)N(2))(2)(C(7)H(9)N)]Cl(2)·0.5H(2)O, there are two crystallographically independent cations and anions and one water mol-ecule in the asymmetric unit. Both Co(III) ions are bonded to two chelating ethylenediamine ligands, one benzylamine molecule and one chloride ion. The crystal packing is through N-H⋯O, N-H⋯Cl and O-H⋯Cl inter-actions.
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The title compound, [Co(C(18)H(18)N(2)O(4))Cl(H(2)O)]·H(2)O, contains a distorted octa-hedral cobalt(III) complex with a 6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-dimethyl-idyne)]diphenolate ligand, a chloride and an aqua ligand, and also a disordered water solvent mol-ecule (half-occupancy). The Co(III) ion is coordinated in an N(2)O(3)Cl manner. Weak O-H⋯O hydrogen bonds may help to st...
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The title compound, [Co(C(2)H(8)N(2))(3)](CO(3))I·4H(2)O, crystallizes with a [Co(en)(3)](3+) cation (en is ethane-1,2-diamine), CO(3) (2-) and I(-) anions and four water mol-ecules in the asymmetric unit. In the cation, the three rings formed by the ethyl-enediamine units and the Co(III) metal ion are in slightly distorted twist conformations. Numerous O-H⋯O, N-H⋯O, N-H⋯I and O-H⋯I inter-molec...
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