Preferential low-pH dissolution of pyroxene in plagioclase–pyroxene mixtures: Implications for martian surface materials

نویسندگان

  • Amy C. McAdam
  • Mikhail Yu. Zolotov
  • Thomas G. Sharp
  • Laurie A. Leshin
چکیده

Acid weathering of plagioclase–pyroxene mixtures has been investigated with an open system kinetic dissolution model. The modeling reveals that elevated plagioclase/pyroxene ratios observed in some low-albedo martian regions and atmospheric dust could be partially caused by preferential dissolution of pyroxenes at pHs below ∼3–4. Surface materials with smaller grain sizes, affected by lower pH fluids, and/or exposed to longer durations of acid weathering would be enriched in plagioclase. If preferential dissolution is responsible for the observed mineral ratios, the dissolution process likely occurred on a large scale, such as weathering by acid atmospheric precipitates. If dissolution was continuous, modeled timeframes required to produce a high plagioclase/pyroxene ratio are short on geologic timescales; however, it is likely that acid weathering on Mars was episodic, possibly occurring over a longer period of time. © 2008 Elsevier Inc. All rights reserved.

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تاریخ انتشار 2008