6-Cyclohexyl-6,7-dihydrodibenzo[c,f][1,5]azabismocin-12(5H)-yl(N→Bi) trifluoromethanesulfonate
نویسندگان
چکیده
In the title compound, [Bi(C(20)H(23)N)(CF(3)SO(3))], the Bi(III) ion shows a distorted pseudo-trigonal-bipyramidal geometry, with two C atoms and a lone electron pair of the Bi atom in equatorial positions and the N and O atoms at the apical positions. The cyclo-hexyl group is disordered over two orientations with site-occupancy factors of 0.600 (14) and 0.400 (14).
منابع مشابه
6-Phenyl-6,7-dihydrodibenzo[c,f][1,5]azabismocin-12(5H)-yl perchlorate
In the title compound, [Bi(C(20)H(17)N)(ClO(4))] or C(20)H(17)BiClNO(4), the Bi(III) ion assumes a distorted ψ trigonal-bipyramidal geometry, with two C atoms and the electron lone pair of the Bi atom at the equatorial positions and an amine N atom and a perchlorate O atom at the apical positions. Weak inter-molecular C-H⋯O hydrogen bonding is present in the crystal structure.
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