Bis{2-[2-(dimethylamino)ethyliminomethyl]-4,6-disulfanylphenolato}cobalt(II) monohydrate
نویسندگان
چکیده
In the title hydrated complex, [Co(C(11)H(15)N(2)OS(2))(2)]·H(2)O, the Co(II) atom (site symmetry 2) is coordinated by two O,N,N'-tridentate Schiff base ligands, resulting in a very distorted cis-CoO(2)N(4) octa-hedral geometry for the metal ion. In the crystal, the water mol-ecule (O-atom site symmetry 2) inter-acts with nearby complex mol-ecules by way of bifurcated O-H⋯(O,S) hydrogen bonds.
منابع مشابه
Bis{2-[3-(dimethylamino)propyliminomethyl]-4,6-disulfanylphenolato}cobalt(II)
In the title mononuclear complex, [Co(C(12)H(17)N(2)OS(2))(2)], the Co(II) atom is four-coordinated by two N,O-bidentate Schiff base ligands, resulting in a slightly distorted trans-CoN(2)O(2) square-planar coordination.
متن کاملBis(2-cyclohexyliminomethyl-4,6-disulfanylphenolato)zinc(II)
In the title complex, [Zn(C(13)H(16)NOS(2))(2)], the Zn(II) ion is four-coordinated by two N,O-bidentate Schiff base ligands, resulting in a distorted trans-ZnN(2)O(2) square-planar geometry for the metal ion.
متن کاملBis(2-cyclohexyliminomethyl-4,6-disulfanylphenolato)nickel(II) acetonitrile solvate
In the title compound, [Ni(C(13)H(16)NOS(2))(2)]·CH(3)CN, the Ni(II) atom is four-coordinated by two N,O-bidentate Schiff base ligands, resulting in a distorted tetra-hedral coordination for the metal ion.
متن کاملBis[4-(dimethylamino)pyridinium] tetrabromidocadmate(II) monohydrate
The Cd atom in the hydrated title salt, (C(7)H(11)N(2))(2)[CdBr(4)]·H(2)O, exists in an approximately tetra-hedral coordination geometry, with Br-Cd-Br angles in the range 105.52 (3)-111.50 (3)°. The cation, anion and water mol-ecule inter-act by O-H⋯Br, N-H⋯Br and N-H⋯O hydrogen bonds, forming a linear chain structure running along the a axis.
متن کاملBis{2-[3-(dimethylamino)propyliminomethyl]-4,6-dihydroselenophenolato}zinc(II)
In the title complex, [Zn(C(12)H(17)N(2)OSe(2))(2)], the Zn(II) ion is six-coordinated by two N,N',O-tridentate Schiff base ligands, resulting in a slightly distorted trans-ZnO(2)N(4) octa-hedral coordination for the metal ion.
متن کامل