Syntheses and Structures of Three Mononuclear Coordination Compounds Containing Six- and Seven-Coordinated Manganese(II) Ions
نویسندگان
چکیده
The reactions o f M n(CF3COO)2 (1) with N,N,N',N'-tetramethylethylenediamine (tmen), 2,2'-bipyridine (bipy) and triethanolamine (tea) yield three new mononuclear coordination compounds: rra«5-[Mn(tmen)2(CF3COO)2] (2), cw-[Mn(bipy)2(C F3COO)2] (3), and [Mn(tea)2](CF3COO)2 (4). The X-ray structures o f the compounds 2, 3, and 4 are described. The seven-coordination o f the manganese(II) ion in 4, as well as the inequivalency o f the two tea molecules coordinated to Mn(II) make this compound unique.
منابع مشابه
Mononuclear and Dinuclear Copper(II) Complexes Containing N, O and S Donor Ligands: Synthesis, Characterization, Crystal Structure Determination and Antimicrobial Activity of [Cu(phen)(tda)].2H2O and [(phen)2Cu(µ-tda)Cu(phen)](ClO4)2.1.5H2O
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