Effect of Temperature on Chemiluminescence of Luminol in Aqueous Aliphatic Amines
نویسنده
چکیده
Effect of temperature on the chemiluminescence (CL) of Luminol in some aqueous aliphatic amines such as ethyl amine (EA), diethyl amine (DEA), and triethyl amine (TEA), have been studied and reported. On the basis of experimental results, it is found that the chemiluminescence intensity initially increased with temperature, attains an optimum value of particular temperature and then decrease on further increase in temperature. It is also found that maximum CL intensity (I max) of chemiluminescence of Luminol founds in diethyl amine.
منابع مشابه
Chemiluminescence Determination of Atropine using Luminol-Hemin-H2O2 System
A sensitive and fast chemiluminescence (CL) method has been described for the direct determination of atropine. The method is based on the quenching effect of atropine on the CL signals of the luminol– H2O2 reaction catalyzed by hemin in an alkaline medium. Hemin could strongly enhance the chemiluminescence of the luminol–H2O2 system. The luminophor of the luminol–H2O2–hemin CL system was ident...
متن کاملEffect of cinnamic and acrylic acids' derivatives on luminol-enhanced chemiluminescence of neutrophils.
Fourteen derivatives of cinnamic and acrylic acids were evaluated for their ability to modulate chemiluminescence, evoked by neutrophils that had been exposed to luminol and phorbol-myristate-acetate. Compounds with one or two hydroxyl groups on the phenyl ring demonstrated significant inhibition of the chemiluminescence, but this inhibition was diminished by methoxylation. Saturation of the do...
متن کاملApplication of Polypyrrole Coated Stainless-Steel Wire to the Headspace Solid-Phase Microextraction of Aliphatic Amines
The electrochemical coating technique was used for the preparation of a polypyrrole coating on a stainless-steel wire, and applied as a fibre for solid phase microextraction (SPME). The polypyrrole fibre was employed for analyzing four volatile aliphatic amines (ethylamine, propylamine, butylamine and pentylamine) in water by headspace SPME using gas chromatography-flame ionization detection (G...
متن کاملDetermination and Spectroscopy of Quantum Yields in Bio/Chemiluminescence via Novel Light-Collection-Efficiency Calibration: Reexamination of The Aqueous Luminol Chemiluminescence Standard
We have developed a luminescence-measurement system for liquid bio/chemiluminescence that can obtain quantitative luminescence spectra as the absolute total number of luminescence photons at each wavelength or photon energy and quantum yields. Calibration of light-collection efficiency in the system is performed with a reference double-plate cell. This method is applicable to sample cells of an...
متن کاملChemiluminescent studies of t-butylhydroperoxide with phenyl hydrazine hydrochloride in the presence and absence of luminol
The chemiluminescence (CL) accompanying the oxidation of phenyl hydrazine with t-butylhydroperoxide in alkaline medium was studied in the presence and absence of luminol. The reaction occurring between phenyl hydrazine and alkaline (KOH) solution of aqueous tbutylhydroperoxide leads to the production of nitrogen gas with simultaneous emission of light (CL), which has been detected by PMT and re...
متن کامل