Microstructure of Al3Sc with ternary rare-earth additions

نویسنده

  • Y. Harada
چکیده

The microstructure of ternary L12-Al3(Sc1 yREy) intermetallics, where RE is one of the rare-earth elements selected from five light (La, Ce, Nd, Sm or Eu) or two heavy lanthanoids (Yb or Lu), was investigated as a function of RE concentration for 0.02 y 0.75. Alloys with light RE show two phases: L12-Al3(Sc,RE) and D019-Al3(RE,Sc) (or C11b-Al4(Eu,Sc)). Alloys with heavy RE exhibit a single L12Al3(Sc,RE) phase. The maximum RE solubility in the L12 phase is very low (<0.4 at.%) for La, Ce, Nd and Eu, low (3.2 at.%) for Sm and complete solid-solution for Yb and Lu. Both lattice parameter and hardness of the L12-Al3(Sc,RE) phases increase linearly with Sm, Yb or Lu concentration, and the magnitude of both effects correlates with the atomic size mismatch between Sc and RE. 2008 Elsevier Ltd. All rights reserved.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Mechanical Properties and Microstructure of Al – Sc with Rare - Earth Element or Al 2 O 3 Additions

Mechanical Properties and Microstructure of Al–Sc with Rare-Earth Element or Al2O3 Additions Richard Albert Karnesky, Jr. Aluminum alloys strengthened with coherent (L12), nanosize Al3Sc precipitates are structural materials that have outstanding strength at ambient and elevated temperatures. They are creep resistant at 300 ◦C and exhibit a threshold stress, below which creep is not measurable....

متن کامل

Microstructure of Al3Sc with ternary transition-metal additions

The microstructure of binary Al3Sc and ternary Al3(Sc1−yXy), where X is one of the transition metals from Group IIIA (Y), IVA (Ti, Zr or Hf) or VA (V, Nb or Ta), was investigated as a function of alloying element concentration for 0.1 y 0.75. Alloys with Group IIIA and IVA additions exhibited a single L12 solid-solution phase with some Kirkendall porosity. At the highest concentration studied, ...

متن کامل

Microstructure and Hardness of Scandium Trialuminide with Ternary Rare-Earth Additions

The microstructure of ternary Al3(Sc1-yREy) intermetallic compounds (where RE is one of the rare-earth elements La, Ce, Nd, Sm, Eu, Yb or Lu), was investigated as a function of RE concentration for 0<y≤0.75. Alloys with La, Ce, Nd, Sm or Eu additions consist of a L12 phase containing a dendritic second phase with D019 (La, Ce, Nd, Sm) or C11b (Eu) structure. Alloys with Yb or Lu additions show ...

متن کامل

THERMAL ANALYSIS AND KINETICS OF THE PRECIPITATION IN WROUGHT Al-Mg, Al-Mg-ScAND Al-Mg-Sc-Me (Me=Zr, Ti) ALLOYS

Precipitation behaviour of wrought Al-6Mg alloys with ternary scandium and quaternary zirconium and titanium has been studied. Hardness measurements and resistivity studies are employed to assess the precipitation behaviour of scandium doped Al-6Mg alloy without or with quaternary additions of zirconium and titanium. Further, the kinetics of precipitations are studied by differential scanning c...

متن کامل

Creep of Al-Sc Microalloys with Rare-Earth Element Additions

Cast and aged Al-Sc microalloys are creep-resistant to 300‰, due to the blocking of dislocations by nanosize, coherent Al3Sc (L12) precipitates. Rare-earth elements substitute for Sc in these precipitates, leading to a higher number density of smaller precipitates, which have a greater lattice-parameter mismatch with Al than in the Al-Sc binary microalloy. This leads to an improvement in both a...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2008