Synthesis, structure, and theoretical investigation of amidinato supported 1,4-disilabenzene.
نویسندگان
چکیده
Reaction of LSi-SiL (1) (L = PhC(NtBu)(2)) with diphenyl alkyne gave the first example of a room temperature stable 1,4-disilabenzene. The compound was characterized by means of single crystal X-ray diffraction studies. NICS (nucleus independent chemical shift) calculations showed that the compound has some aromatic character.
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ورودعنوان ژورنال:
- Chemical communications
دوره 46 32 شماره
صفحات -
تاریخ انتشار 2010